{"id":168,"date":"2011-12-29T15:55:27","date_gmt":"2011-12-29T06:55:27","guid":{"rendered":"https:\/\/japan-scripps.chem-station.com\/?p=168"},"modified":"2014-07-23T19:46:04","modified_gmt":"2014-07-23T10:46:04","slug":"rebek-lab%e3%81%ab%e7%95%99%e5%ad%a6%e3%81%97%e3%81%a6%ef%bc%9a%e5%b1%b1%e4%b8%ad%e6%ad%a3%e9%81%93","status":"publish","type":"post","link":"https:\/\/japan-scripps.chem-station.com\/?p=168","title":{"rendered":"Rebek Lab\u306b\u7559\u5b66\u3057\u3066\uff1a\u5c71\u4e2d\u6b63\u9053"},"content":{"rendered":"<ul>\n<li>\u30b9\u30af\u30ea\u30d7\u30b9\u7814\u7a76\u6240\u3068\u306f<\/li>\n<\/ul>\n<p>\u79c1\u304c\u898b\u3066\u611f\u3058\u305f\u30b9\u30af\u30ea\u30d7\u30b9\u7814\u7a76\u6240\uff08The Scripps Research Institute, \u4ee5\u4e0bTSRI\uff09\u306f\uff0c\u201c\u4e00\u6d41\u306e\u7814\u7a76\u8005\u306b\u6700\u9ad8\u306e\u7814\u7a76\u74b0\u5883\u3092\u63d0\u4f9b\u3059\u308b\u7814\u7a76\u6240\u201d \u3067\u3042\u308b\uff0e \u3000\u3042\u308b\u3068\u304d\uff0c\u7559\u5b66\u4e2d\u306e\u30dc\u30b9\u3067\u3042\u3063\u305fJulius Rebek, Jr. \u6559\u6388\u306b\u300c\u3069\u3046\u3057\u3066TSRI \u306b\u79fb\u3063\u3066\u304d\u305f\u306e\u3067\u3059\u304b\uff1f\u300d\u3068\uff0c1996 \u5e74\u306b\u524d\u4efb\u5730\u3067\u3042\u308b\u30dc\u30b9\u30c8\u30f3\u306e\u30de\u30b5\u30c1\u30e5\u30fc\u30bb\u30c3\u30c4\u5de5\u79d1\u5927\u5b66\u3088\u308aTSRI 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\u6559\u6388\u306f\u30b9\u30ab\u30c3\u30b0\u30b9\u8ca1\u56e3\u3088\u308a\u7814\u7a76\u8cbb\u3092\u652f\u63f4\u3055\u308c\u3066\u3044\u308b\uff09\uff0e\u305d\u3057\u3066\uff0c\u300c\u81ea\u5206\u306e\u3084\u308a\u305f\u3044\u7814\u7a76\u306b\u591a\u304f\u306e\u6642\u9593\u3092\u5272\u304f\u3053\u3068\u304c\u3067\u304d\u308b\u4eca\u306e\u74b0\u5883\u306b\u305f\u3044\u3078\u3093\u6e80\u8db3\u3057\u3066\u3044\u308b\u300d\u3068\u3082\u3044\u3063\u3066\u3044\u305f\uff0e \u3000\u4e8b\u5b9f\uff0c\u79c1\u304cTSRI \u306b\u5728\u7c4d\u3057\u3066\u3044\u308b\u3042\u3044\u3060\uff0cRebek \u6559\u6388\u306f\u3042\u308c\u3060\u3051\u8457\u540d\u306a\u5148\u751f\u3067\u3042\u308b\u306b\u3082\u304b\u304b\u308f\u3089\u305a\uff0c1 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\u6559\u6388\u306f\u3053\u306e\u5206\u91ce\u306e\u30d1\u30a4\u30aa\u30cb\u30a2\u3067\uff0c\u7814\u7a76\u306e\u7aef\u7dd2\u306f\u30de\u30b5\u30c1\u30e5\u30fc\u30bb\u30c3\u30c4\u5de5\u79d1\u5927\u5b66\u5728\u4efb\u4e2d\u306e1993 \u5e74\u306b\u767a\u8868\u3057\u305f\u30c6\u30cb\u30b9\u30dc\u30fc\u30eb\u578b\u30ab\u30d7\u30bb\u30eb\u306b\u307e\u3067\u9061\u308b\uff0e\u305d\u306e\u3042\u3068\u3082\uff0c\u30bd\u30d5\u30c8\u30dc\u30fc\u30eb\u578b\u30ab\u30d7\u30bb\u30eb\uff0c\u30b7\u30ea\u30f3\u30c0\u30fc\u30c6\u30fc\u30de\u306e\u8a2d\u5b9a\u306f\u304b\u306a\u308a\u81ea\u7531\u5ea6\u304c\u9ad8\u304f\uff0c\u7814\u7a76\u5ba4\u306e\u6d41\u308c\u306b\u5247\u3057\u305f\u3082\u306e\u3067\u3042\u308c\u3070\uff0c\u81ea\u3089\u306e\u767a\u6848\u3067\u6bd4\u8f03\u7684\u5bb9\u6613\u306b\u30d7\u30ed\u30b8\u30a7\u30af\u30c8\u3092\u59cb\u3081\u308b\u3053\u3068\u304c\u3067\u304d\u308b\uff0e\u591a\u304f\u306e\u4eba\u306f\u5e38\u66422 \u500b\u4ee5\u4e0a\u306e\u7814\u7a76\u30c6\u30fc\u30de\u3092\u4e26\u884c\u3057\u3066\u9032\u3081\u3066\u3044\u3066\uff0c\u30c6\u30fc\u30de\u306b\u5fdc\u3058\u3066\u30c1\u30fc\u30e0\u3092\u7d44\u3093\u3060\u308a\uff0c \u500b\u4eba\u3067\u9032\u3081\u305f\u308a\u3059\u308b\uff0e\u305d\u306e\u30c1\u30fc\u30e0\u7de8\u6210\u306b\u3064\u3044\u3066\u3082Rebek \u6559\u6388\u304c\u6307\u793a\u3059\u308b\u3053\u3068\u306f\u5c11\u306a\u304f\uff0c\u307b\u3068\u3093\u3069\u306f\u5404\u4eba\u306e\u5224\u65ad\u306b\u3088\u3063\u3066\u884c\u308f\u308c\u308b\uff0e \u3000\u5e78\u3044\uff0c\u79c1\u306e\u5834\u5408\u306f\u307b\u304b\u306e\u535a\u58eb\u7814\u7a76\u54e1\u3068\u306e\u5171\u540c\u7814\u7a76\uff0c\u5927\u5b66\u9662\u306e\u5b66\u751f\u3068\u306e\u5171\u540c\u7814\u7a76\uff0c\u305d\u3057\u3066\u5358\u72ec\u3067\u306e\u7814\u7a76\u3092\u4f53\u9a13\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u305f\uff0e\u305d\u308c\u3089\u306b\u306f\uff0c\u305d\u308c\u305e\u308c\u306b\u9055\u3063\u305f\u9762\u767d\u3055\u304c\u3042\u308a\uff0c\u3088\u3044\u7d4c\u9a13\u3068\u306a\u3063\u305f\uff0e<\/p>\n<p>\u6700\u8fd1\u306e\u6210\u679c<\/p>\n<p>\u3053\u3053\u6570\u5e74\u306f\u3001\uff11\uff19\uff19\uff18\u5e74\u306b\u306f\u3058\u3081\u3066\u5831\u544a\u3057\u305f\u30b7\u30ea\u30f3\u30c0\u30fc\u578b\u30ab\u30d7\u30bb\u30eb\u3014<em>Nature<\/em>, <strong>394, <\/strong>764\uff081998\uff09\u3015\u306b\u95a2\u9023\u3057\u305f\u7814\u7a76\u304c\u30ab\u30d7\u30bb\u30eb\u7814\u7a76\u306e\u4e2d\u5fc3\u3068\u306a\u3063\u3066\u3044\u305f\uff0e\u591a\u304f\u306e\u8d85\u5206\u5b50\u30ab\u30d7\u30bb\u30eb\u306e\u30ad\u30e3\u30d3\u30c6\u30a3\u30fc\uff08\u30ab\u30d7\u30bb\u30eb\u306e\u4e2d\u7a7a\uff09\u304c\u7403\u72b6\u3067\u3042\u308b\u306e\u306b\u5bfe\u3057\u3066\uff0c\u3053\u306e\u30ab\u30d7\u30bb\u30eb\u306e\u30ad\u30e3\u30d3\u30c6\u30a3\u30fc\u306f\u5186\u7b52\u72b6\u3067\u7d30\u9577\u3044\uff08\u7d04420\u00c5<sup>3<\/sup>\uff09\uff0e\u305d\u306e\u305f\u3081\uff0c\u3053\u306e\u30ad\u30e3\u30d3\u30c6\u30a3\u30fc\u306b\u5305\u63a5\u3055\u308c\u305f\uff08\u9589\u3058\u8fbc\u3081\u3089\u308c\u305f\uff09\u30b2\u30b9\u30c8\u5206\u5b50\u306e\u904b\u52d5\u306f\u898f\u5236\u3055\u308c\u308b\uff0e\u3053\u306e\u30b7\u30ea\u30f3\u30c0\u30fc\u578b\u30ab\u30d7\u30bb\u30eb\u306b\u3088\u3063\u3066\u63d0\u4f9b\u3055\u308c\u308b\u7279\u7570\u306a\u30ad\u30e3\u30d3\u30c6\u30a3\u30fc\u306e\u7279\u8272\u3092\u751f\u304b\u3057\u3001\u591a\u304f\u306e\u8208\u5473\u6df1\u3044\u7269\u7406\u6709\u6a5f\u5316\u5b66\u7684\u73fe\u8c61\u304c\u89b3\u5bdf\u3055\u308c\u3066\u3044\u308b\u3002\u305f\u3068\u3048\u3070\uff0c\u30ad\u30e3\u30d3\u30c6\u30a3\u30fc\u306e\u4e0d\u6589\u8a8d\u8b58\u5834\u3068\u3057\u3066\u306e\u5229\u7528<strong>\u3014<\/strong><em>J<\/em><em>. Am. Chem. Soc.<\/em>, <strong>125, <\/strong>13981\uff08 2003\uff09\u3015\u3084\uff0c\u30b2\u30b9\u30c8\u5206\u5b50\u306e\u914d\u5411\u3084\u914d\u7f6e\u306b\u8d77\u56e0\u3059\u308b\u3053\u308c\u307e\u3067\u306b\u4f8b\u306e\u306a\u3044\u7570\u6027\u4f53\u306e\u89b3\u6e2c\u3014<em>J. Am. Chem. Soc.<\/em>, <strong>125, <\/strong>6239\uff08 2003\uff09\uff0c <em>Proc. Natl. Acad. Sci. USA<\/em>, <strong>101, <\/strong>2669\uff08 2004\uff09\u3015\u306a\u3069\u304c\u3042\u3052\u3089\u308c\u308b\uff0e\u3082\u3046\u4e00\u3064\u306e\u7814\u7a76\u306e\u67f1\u306f\u6a5f\u80fd\u6027\u30ad\u30e3\u30d3\u30bf\u30f3\u30c9\u306b\u95a2\u3059\u308b\u7814\u7a76\u3067\u6c34\u6eb6\u6027\u306e\u30ad\u30e3\u30d3\u30bf\u30f3\u30c9\u306b\u3088\u308b\u5206\u5b50\u8a8d\u8b58\u3014Angew<em>. Chem., Int. Ed.<\/em>, <strong>42, <\/strong>3150\uff08 2003\uff09\u3015\u3084\uff0c\u5b98\u80fd\u57fa\u5316\u3055\u308c\u305f\u30ad\u30e3\u30d3\u30bf\u30f3\u30c9\u5185\u3067\u306e\u5316\u5b66\u53cd\u5fdc\u306e\u52a0\u901f\u3014<em>J. Am. Chem. Soc.<\/em>, <strong>125, <\/strong>14682 \uff08 2003\uff09\u3015\u3068\u3044\u3063\u305f\u6210\u679c\u3092\u5831\u544a\u3057\u3066\u3044\u308b\uff0e<\/p>\n<p>\u5b9f\u9a13\u74b0\u5883<\/p>\n<p>\u5927\u5b66\u9662\u751f\u3084\u535a\u58eb\u7814\u7a76\u54e1\u306b\u306f\u3001\u30c9\u30e9\u30d5\u30c8\u3068\u5b9f\u9a13\u53f0\u3001\u305d\u3057\u3066\u30c7\u30b9\u30af\u30ef\u30fc\u30af\u3092\u3059\u308b\u30b9\u30da\u30fc\u30b9\u304c\u4e0e\u3048\u3089\u308c\u308b\uff0e\u6e21\u7c73\u5f53\u521d\uff0c \u65e5\u672c\u306e\u72ed\u3044\u5b9f\u9a13\u30b9\u30da\u30fc\u30b9\u306b\u6163\u308c\u3066\u3044\u305f\u79c1\u306b\u3068\u3063\u3066\u306f\u306a\u3093\u3068\u3082\u8d05\u6ca2\u306a\u5e83\u3055\u3067\u3042\u3063\u305f\uff0e\u30a8\u30d0\u30dd\u30ec\u30fc\u30bf\u30fc\u3084HPLC \u306a\u3069\u306e\u6a5f\u5668\u306f\u7814\u7a76\u5ba4\u5185\u3067\u5171\u901a\u3067\u4f7f\u7528\u3057\u3066\u3044\u308b\uff0e \u3000\u30ec\u30d9\u30c3\u30af\u7814\u3067\u306e\u7814\u7a76\u306b\u304a\u3044\u3066\u6700\u3082\u4f7f\u7528\u983b\u5ea6\u306e\u9ad8\u3044NMR \u306b\u95a2\u3057\u3066\u306f\uff0c 600MHz\uff08 Bruker\uff09\u306e\u88c5\u7f6e\u30921 \u65e5\u4e2d\u307b\u307c\u81ea\u7531\u306b\u4f7f\u3046\u3053\u3068\u304c\u3067\u304d\u308b\uff0e\u307e\u305f\uff0c\u7279\u6b8a\u306a\u6e2c\u5b9a\u3092\u884c\u3046\u5834\u5408\u306b\u306f\uff0c\u5c02\u9580\u306e\u6280\u5b98\u304c\u89aa\u5207\u306b\u30b5\u30dd\u30fc\u30c8\u3057\u3066\u304f\u308c\u308b\uff0e<\/p>\n<p>&nbsp;<\/p>\n<p>\u30bc\u30df<\/p>\n<p>\u30ec\u30d9\u30c3\u30af\u7814\u306e\u7814\u7a76\u5831\u544a\u4f1a\u306f\u5e74\u306b\uff14\u56de\u3001\u5b66\u4f1a\u5f62\u5f0f\u3067\u884c\u308f\u308c\u308b\uff0e Rebek \u6559\u6388\u306e\u90fd\u5408\u306b\u5408\u308f\u305b\u3066\u5831\u544a\u4f1a\u306e\u958b\u50ac\u65e5\u304c\u6c7a\u3081\u3089\u308c\uff0c\u5927\u5b66\u9662\u751f\uff0c\u535a\u58eb\u7814\u7a76\u54e1\u306f\u305d\u308c\u305e\u308c\u306e\u7814\u7a76\u6210\u679c\u3092\u7d0420 \u5206\u3067\u53e3\u982d\u767a\u8868\u3059\u308b\uff0e\u307e\u305f\u5e74\u306b2 \u56de\uff0c\u7814\u7a76\u306e\u9032\u884c\u72b6\u6cc1\u3092\u518a\u5b50\u306b\u307e\u3068\u3081\u305f\u300cProgress Report\u300d\u306e\u63d0\u51fa\u304c\u6c42\u3081\u3089\u308c\u308b\uff0e\u3000\u8ad6\u6587\u7d39\u4ecb\u306e\u30bc\u30df\u306f\uff0c\u5927\u5b66\u9662\u751f\u3068\u535a\u58eb\u7814\u7a76\u54e1\u306e\u307f\u3067\u9031\u306b1\u56de\u306e\u30da\u30fc\u30b9\u3067\u884c\u3063\u3066\u3044\u308b\uff0e\u307e\u305f\uff0c\u3068\u304f\u306b\u535a\u58eb\u7814\u7a76\u54e1\u306e\u5834\u5408\u306fRebek \u6559\u6388\u306e\u307b\u3046\u304b\u3089\u7814\u7a76\u306e\u9032\u884c\u72b6\u6cc1\u3092\u5c0b\u306d\u3066\u304f\u308b\u3053\u3068\u304c\u7a00\u306a\u306e\u3067\uff0c\u7814\u7a76\u306e\u9032\u884c\u72b6\u6cc1\u306b\u3064\u3044\u3066\u30c7\u30a3\u30b9\u30ab\u30c3\u30b7\u30e7\u30f3\u3057\u305f\u3044\u3068\u304d\u306b\u306f\u81ea\u5206\u304b\u3089\u6559\u6388\u5ba4\u3092\u8a2a\u306d\u3066\u884c\u304f\u5fc5\u8981\u304c\u3042\u308b\uff0e\u305d\u306e\u983b\u5ea6\u306f\u4eba\u306b\u3088\u3063\u3066\u7570\u306a\u308b\u304c\uff0c Rebek \u6559\u6388\u306f\u5fd9\u3057\u3044\u3068\u304d\u3067\u3082\u975e\u5e38\u306b\u3066\u3044\u306d\u3044\u306b\u5fdc\u5bfe\u3057\u3066\u304f\u308c\u3066\uff0c\u3044\u3064\u3082\u7684\u78ba\u306a\u52a9\u8a00\u3092\u4e0e\u3048\u3066\u304f\u308c\u308b\uff0e\u305d\u306e\u305f\u3081\uff0c\u79c1\u306f\u597d\u307e\u3057\u3044\u7d50\u679c\u304c\u3067\u305f\u3068\u304d\u3070\u304b\u308a\u3067\u306f\u306a\u304f\uff0c\u7814\u7a76\u304c\u716e\u8a70\u307e\u3063\u305f\u3068\u304d\u3082\uff0c\u304b\u306a\u308a\u306e\u983b\u5ea6\u3067\u6559\u6388\u5ba4\u3078\u62bc\u3057\u304b\u3051\u3066\u3044\u305f\uff0e<\/p>\n<p>&nbsp;<\/p>\n<p>\u30ec\u30d9\u30c3\u30af\u7814\u3067\u5408\u6210\u3055\u308c\u305f\u30ab\u30d7\u30bb\u30eb<\/p>\n<p>a\uff09\u30c6\u30cb\u30b9\u30dc\u30fc\u30eb\u578b\u30ab\u30d7\u30bb\u30eb\uff0e\u30e1\u30bf\u30f3\u306a\u3069\u5206\u5b50\u30b5\u30a4\u30ba\u306e\u5c0f\u3055\u306a\u30b2\u30b9\u30c8\u3092\u5305\u63a5\u3059\u308b\uff0e b\uff09\u30bd\u30d5\u30c8\u30dc\u30fc\u30eb\u578b\u30ab\u30d7\u30bb\u30eb\uff0e\u8907\u6570\u306e\u30b2\u30b9\u30c8\u306e\u5305\u63a5\u3082\u53ef\u80fd\u3067\uff0c\u5316\u5b66\u53cd\u5fdc\u306e\u52a0\u901f\u52b9\u679c\u3082\u767a\u898b\u3055\u308c\u305f\uff0e c\uff09\u30b7\u30ea\u30f3\u30c0\u30fc\u578b\u30ab\u30d7\u30bb\u30eb\uff0e \u7d30\u9577\u3044\u30ad\u30e3\u30d3\u30c6\u30a3\u30fc\u3092\u3082\u3064\u305f\u3081\uff0c\u5305\u63a5\u3055\u308c\u305f\u30b2\u30b9\u30c8\u306e\u5206\u5b50\u904b\u52d5\u3092\u898f\u5236\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u308b\uff0e<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u30b9\u30af\u30ea\u30d7\u30b9\u7814\u7a76\u6240\u3068\u306f \u79c1\u304c\u898b\u3066\u611f\u3058\u305f\u30b9\u30af\u30ea\u30d7\u30b9\u7814\u7a76\u6240\uff08The Scripps Research Institute, \u4ee5\u4e0bTSRI\uff09\u306f\uff0c\u201c\u4e00\u6d41\u306e\u7814\u7a76\u8005\u306b\u6700\u9ad8\u306e\u7814\u7a76\u74b0\u5883\u3092\u63d0\u4f9b\u3059\u308b\u7814\u7a76\u6240\u201d \u3067\u3042\u308b\uff0e \u3000\u3042\u308b\u3068\u304d\uff0c\u7559\u5b66\u4e2d\u306e\u30dc\u30b9 &hellip; <a href=\"https:\/\/japan-scripps.chem-station.com\/?p=168\" class=\"more-link\">Continue reading <span class=\"screen-reader-text\">Rebek Lab\u306b\u7559\u5b66\u3057\u3066\uff1a\u5c71\u4e2d\u6b63\u9053<\/span> <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":2,"featured_media":169,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":false,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[4],"tags":[6,5],"class_list":["post-168","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-lab-reports","tag-masamichi-yamanaka","tag-rebek"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/i0.wp.com\/assets.japan-scripps.chem-station.com\/uploads\/2011\/12\/rebek_yamanaka.png?fit=658%2C236&ssl=1","jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/p94ZQN-2I","jetpack-related-posts":[],"_links":{"self":[{"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=\/wp\/v2\/posts\/168","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=168"}],"version-history":[{"count":6,"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=\/wp\/v2\/posts\/168\/revisions"}],"predecessor-version":[{"id":208,"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=\/wp\/v2\/posts\/168\/revisions\/208"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=\/wp\/v2\/media\/169"}],"wp:attachment":[{"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=168"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=168"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/japan-scripps.chem-station.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=168"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}